At Lake Tegel in Berlin, Germany, drinking water is produced by induced bank filtration. Under such increased infiltration conditions, it is very important to understand the natural purification processes in the upper littoral zone (sediment depth of about 0–30 cm) in order to maintain a high drinking water quality. We therefore analyzed the pore water and measured the redox potential at Lake Tegel regularly to detect fluctuations in the concentrations of physicochemical parameters due to seasonal variations in the redox potential. The redox potential is not only influenced by the biological activity of the interstitial biocoenosis, but also by hydraulic conditions that occasionally produce unsaturated zones leading to an intrusion of gaseous oxygen. The result is an increase in the redox potential, which declines during the summer due to intensive dissimilatory reduction and microbial activity, thus leading to distinctly anaerobic conditions. When this is the case, the oxygen supplied by primary production and bioturbation cannot meet the oxygen demand needed for the mineralization of organic material. Negative redox values (minimal –200 mV) are accompanied by increases in nitrite (max. conc. 150 µg/L) and ammonium levels (max. conc. 0.45 mg/L), while the nitrate concentrations decreased (min. conc. 0.2 mg/L). This indicates that processes such as denitrification and ammonification occur, and that, after depletion of free oxygen reserves, other electron acceptors, such as nitrate and also heavy metal ions (Fe3+), are used.

Several kinds of managed aquifer recharge techniques provide very good purification of surface water since more than 100 years. In order to maintain a reliable supply of clean water, they are becoming increasingly popular all over the world. These methods require low technical effort. At Aquifer Storage and Recovery and ponded infiltration the recharged amounts are technically controlled. The infiltration water has to be pumped and often pretreated. At bank filtration this is dispensable, the approach, of using existing surface water bodies is even more consequent. Exemplarily, at a test site at Lake Tegel, Berlin, Germany, the hydraulic processes are modelled. By means of 3D long term regional and transient hydraulic modelling it was detected that the existing approaches for determining the leakance induce large errors in the water balance and describe the infiltration zone insufficiently. The leakance could be identified to be triggered by the groundwater table, causing air exchange and intrusion of atmospheric oxygen, which reduces clogging by altered redox conditions by at least one order of magnitude. This causes that changes of the groundwater table are mitigated much more than previously assumed. Taking these findings into account, a transient water balance is determined and bank filtration ratios are quantified. A new inverse modelling concept has been developed and applied to a 3D short term local and transient hydraulic model. It comprises spatially distributed pilot points and overparameterisation constrained by regularisation and calibration to head differences. Significance of the results is demonstrated by cross validation. With this approach the spatial distribution of an aquitard have been identified with high precision. The highly transient and heterogeneous flow conditions are specified and a new viewpoint on the geologic formation of Lake Tegel is obtained. The good fit of modelled and observed breakthrough curves of 18O, chloride and temperature by just using transferred parameters obtained with the previous hydraulic methods, show the very good model performance and predictive capabilities. The intrusion of atmospheric oxygen into the unsaturated zone is identified to be the principal redox determining factor during infiltration. Previously inconsistent and also local geochemical conditions are identified to be determined by interaction of infiltration processes with the spatial extent of the aquitard. A theory for chemical clogging of abstraction wells is developed, identifying the strong vertical redox zoning as principal factor of influence.

In several slow-sand-filter experiments the behaviour of phages during the subsurface passage was measured and modelled. Here the focus is on the effect of the velocity. The observed data show a strong effect of decreasing filter efficiency with increasing velocity. Using a modelling approach, which is based on the transport differential equation, the theoretical influence of velocity on filter efficiency is examined. Finally an extrapolation of the results to large scale filtration units or bank filtration processes is attempted.

The aim of the study was to evaluate the influence of variable redox conditions on a number of pharmaceutically active compounds, namely carbamazepine, phenazone and AMDOPH (1-acetyl-1-methyl-2-dimethyl-oxymoyl2-phenylhydrazide) below an artificial recharge pond in Berlin. The redox conditions change seasonally, mainly as a result of temperature changes of 0 to 24°C in the infiltrate. Aerobic conditions prevail in winter, while manganese reducing conditions are reached below the pond in summer. Phenazone is redox sensitive and was generally fully degraded before reaching the first groundwater well as long as oxygen was present. When conditions turned anaerobic, phenazone was not fully eliminated. AMDOPH (1-acetyl-1-methyl-2-dimethyl-oxymoyl2-phenylhydrazide) and carbamazepine are very persistant drug residues. However, results suggest that AMDOPH may be degradable under certain favourable conditions (i.e. aerobic conditions; relatively high temperatures, low recharge rates), but further studies will need to verify this statement.

Microcystins (MCYST) are a group of toxic substances produced by cyanobacteria (‘blue-green-algae’). In case of cyanobacterial blooms microcystin concentrations in surface waters may reach values far above the value proposed as provisional guideline for drinking water by the WHO of 1 µg/L for MCYST-LR. For drinking water production via underground passage it is therefore necessary to ensure removal to a large extent. For this reason experiments with extracellular microcystins were conducted in the laboratory as well as in a natural setting on the UBA’s (German Federal Environmental Agency) experimental field for simulation of underground passage. Laboratory batch experiments showed that adsorption of microcystins can be neglected in sandy material (kd < 1 cm³/g). Batch and column experiments identified biodegradation as the predominant elimination process in these sediments. The degradation rates derived from laboratory column experiments as well as semi-technical scale enclosure experiments varied between 0.2 d–1 and 18 d–1. In the worst case this means a half life of 2.8 days, so that under aerobic conditions contact times of several days should be sufficient to eliminate MCYST to an extent safe for use as drinking water.

Successful predictions of the fate and transport of solutes during bank filtration and artificial groundwater recharge depends on the availability of accurate transport parameters. We expand the CXTFIT code (Toride et al., 1995) in order to improve the handling by pre- and post processing modules under Microsoft EXCEL. Inverse modelling results of column experiments with tracers, pharmaceutical residuals and algae toxins demonstrate the applicability of the advanced simulation tool.

More than two years of monitoring data from a bank filtration site in Berlin, Germany, and a long retention soil column system (30 m) were analyzed to study the influence of redox conditions on the degradation of bulk organics. Dissolved organic carbon (DOC), UV-absorption at 254 nm (UVA254) and liquid chromatography with online carbon detection (LC-OCD) was employed to receive qualitative and quantitative information about the fate of different fractions of DOC. It was found that the kinetics of DOC-degradation depend significantly on the dominant redox conditions during infiltration. A faster mineralization of biodegradable DOC was observed during oxic soil passage (~1 month). Anoxic infiltration led to a comparable residual DOC-concentration, but 3-6 months were required for complete removal of biodegradable DOC (BDOC). LC-OCD measurements revealed that the fraction of polysaccharides (PS) is removed very fast during infiltration in the field. Under strictly anoxic conditions the PS were more stable. The fractions of humic substances, building blocks and low molecular weight acids were degraded partially, independently from the redox potential, while the change in aromaticity of the residual DOC was influenced by the dominant redox conditions.

The interest in natural surface-water treatment techniques such as bank filtration and artificial ground water replenishment has increased with the growing worldwide need for clean drinking water. After detecting a number of pharmaceutical residues in groundwater samples from a bank filtration site in Berlin, Germany, the research on these compounds has focused on investigating their transport behavior during the infiltration process. In the studies presented in this paper, the fate of six pharmaceutical residues detected at concentrations up to the µg/L-level in Berlin’s surface waters was investigated. During bank filtration, the analgesic drugs diclofenac and propyphenazone, the antiepileptic drugs carbamazepine and primidone and the drug metabolites clofibric acid and 1-acetyl-1-methyl-2-dimethyl-oxamoyl-2-phenylhydrazide (AMDOPH) were found to leach from the surface water into the groundwater aquifers. They also occur at low ng/Lconcentrations in the receiving water-supply wells. Other compounds namely the antiphlogistic drug indometacine and the blood regulating drug bezafibrate which are also detected at concentrations up 100 ng/L in the surface water are efficiently removed by bank filtration. Thus, they have not been detected downstream of the first two monitoring wells. In conclusion, bank filtration was found to decrease the concentrations of some drug residues (e.g. of diclofenac, carbamazepine) or even to remove selected compounds (e.g. bezafibrate, indometacine). However, a complete removal of all potential pharmaceutical residues by bank filtration cannot be guaranteed.