Bank filtration and artificial ground water recharge are important, effective, and cheap techniques for surface water treatment and removal of microbes, as well as inorganic, and some organic, contaminants. Nevertheless, physical, chemical, and biological processes of the removal of impurities are not understood sufficiently. A research project titled Natural and Artificial Systems for Recharge and Infiltration attempts to provide more clarity in the processes affecting the removal of these contaminants. The project focuses on the fate and transport of selected emerging contaminants during bank filtration at two transects in Berlin, Germany. Several detections of pharmaceutically active compounds (PhACs) in ground water samples from bank filtration sites in Germany led to furthering research on the removal of these compounds during bank filtration. In this study, six PhACs including the analgesic drugs diclofenac and propyphenazone, the antiepileptic drugs carbamazepine and primidone, and the drug metabolites clofibric acid and 1-acetyl–1-methyl–2-dimethyloxamoyl– 2-phenylhydrazide were found to leach from the contaminated streams and lakes into the ground water. These compounds were also detected at low concentrations in receiving public supply wells. Bank filtration either decreased the concentrations by dilution (e.g., for carbamazepine and primidone) and partial removal (e.g., for diclofenac), or totally removed PhACs (e.g., bezafibrate, indomethacine, antibiotics, and estrogens). Several PhACs, such as carbamazepine and especially primidone, were readily transported during bank filtration. They are thought to be good indicators for evaluating whether surface water is impacted by contamination from municipal sewage effluent or whether contamination associated with sewage effluent can be transported into ground water at ground water recharge sites.

The effect of oscillating pumping regimes at the bank filtration site in Berlin Tegel is examined via a scenario based modelling study. There are several scenarios for the pumping regimes, some adopted from the operation of the plant by the Berlin Water Works (BWB), some hypothetical with a regular oscillating regime. A horizontal 2D model of the lower aquifer is set-up, in which the third type boundary condition is used to mimic the influence of an irregularly shaped till layer, overlying the main aquifer. Model results in form of flowpaths are presented for several pumping scenarios. They reveal that there is a substantial influence of the pumping regime on the flowpaths in the vicinity of the well gallery, while in the farfield, including the bank of the surface water body (here: Lake Tegel) the oscillating effect is rather small. It depends very much on the infiltration position on the bank, whether traveltime through the aquifer changes as effect of irregular pumping.

The effect of oscillating pumping regimes at the bank filtration site in Berlin Tegel is examined via a scenario based modelling study. Several scenarios for the pumping regimes are calculated, some adopted from the operation of the plant by the Berlin Water Works (BWB), some hypothetical with a regular oscillating regime. Two of these are presented here. A horizontal 2D model of the lower aquifer is set-up, in which the third type boundary condition is used to mimic the influence of an irregularly shaped till layer, overlying the main aquifer. Model results in form of flowpaths are presented for several pumping scenarios. They reveal that there is a substantial influence of the pumping regime on the flowpaths in the vicinity of the well gallery, while in the far field, including the bank of the surface water body (here: Lake Tegel) the oscillating effect is rather small. It depends very much on the infiltration position on the bank, whether traveltime through the aquifer changes as effect of oscillating pumping regime.

Bank fillration provides an important drinking water source to the city of Berlin. 56% of the drinking water is derived from bank filtration (the remainder is 14% replenished groundwater and 30% natural groundwater) [1]. At most bank filtration sites, the surface water contains portions of sewage treatment plant effluent (Lake Tegel 10-30%, [2]). Due to water recycling, the introduction of effluent organic matter (EfON) and persistent trace pollutants in the drinking water may be a concern. The project "Organic Substances in Bank filtration and Groundwater Recharge Process Studies" at the Department for Water Quality Control (DWQC) at the Technical University of Berlin is part of the "Natural and Artificial Systems for Recharge and lnfiltration (NASRI)' - project of the Berlin Centre of Competence for Water [3]. The research objectives of this part of the project are to study the removal of bulk organics (dissolved organic carbon (DOC) and EfOM) and trace organics at three field sites with different characteristics. Since the processes during bank filtration are very complex, it is difficult to predict bulk organic composition in the bank filtrale or to estimate important factors of influence for the degradation of trace compounds. For instance, it was shown in previous studies, that iodinated x-ray contrast medias are deiodinated under teductive conditions. Therefore, a bank filtration under anoxic or even anaerobic conditions would provide the removal of these trace pollutants. In addition to lhe redox state, factors such as retention time, initial degradable carbon . concentration, soil properties and hydrogeologlcal conditions may affect the final concentration. In order to be able to prevent the intrusion of persistent pollutants into the drinking water, lhe factors of influence are studied for a few model compounds that represent groups of trace pollutants. This will provide a tool that can be merged with hydrogeological models and soil properties to predict the removal efficiency of a given field site. To fulfill these objectives this research is presently investating: (i) the differences in bulk organic composition and trace organic concentration related to bank filtration conditions at three different field sites in Berlin, (ii) the simulation of a bank filtration site with a 30m soil column (elimination of hydrogeological variables).

Bank filtration and artificial recharge provides an important drinking water source to the city of Berlin. Due to water recycling, the introduction of persistent trace pollutants (e.g. pharmaceuticals) in the drinking water may be a concern. The project “Organic Substances in Bank filtration and Groundwater Recharge - Process Studies” at the Technical University of Berlin is part of the “Natural and Artificial Systems for Recharge and Infiltration (NASRI)”-project of the Berlin Centre of Competence for Water. The research objectives of this part of the project are to study the removal of bulk and trace organics at different field sites with different characteristics in Berlin. In Berlin’s public drinking water supply nearly 70% of the 220 Mio m3 per year originate from bank filtration and groundwater recharge (~56% from bank filtration and ~14% from groundwater recharge (BWB 2003)). Since the 19th century Berlin has relied on bank filtration with retention times of several months to produce “new” ground water. A semi-closed urban water cycle has been created with the growth of the city. At some bank filtration sites the surface water is strongly influenced by highly treated domestic waste water effluent (e.g. 15-30% in Lake Tegel) (Ziegler et al. 2002). Despite this indirect potable reuse, the bank filtration system continues to provide high quality water which is distributed without chlorination. This unique situation in Berlin was an interesting field site for a research project of the Berlin Center of Competence for Water. Recently, the break through of organic trace pollutants in bank filtration systems has been studied in various research projects. Especially, since improved analytical methods can detect in ranges below 1µg/l. Since the processes during bank filtration are very complex, it is difficult to predict the fate of trace organics during bank filtration or to estimate important factors of influence for their degradation. In addition to redox state, factors such as retention time, initial degradable carbon concentration, soil properties and hydrogeological conditions may affect the final concentration. Many studies revealed positive findings of pharmaceuticals, pesticides or industrial chemicals (Hiemstra et al. 2003, Heberer et al. 2001, Verstraeten et al. 2002) in bank filtrate. Compounds like carbamazepine and clofibric acid were reported to be partly recalcitrant during underground transport (Stan and Linkerhäger 1994, Ternes et al. 2002). Furthermore, Ternes and Hirsch (2000) reported the occurrence of x-ray contrast media in surface waters and in surface water influenced groundwaters, where they constitute a major fraction of the adsorbable organic iodine (AOI). The contrast media were found to be very polar, persistent and difficult to remove in wastewater treatment (Jekel and Wischnack 2000). Hartig (2000) reported the break through of antibiotic sulfonamides from surface water to monitoring wells more than 50 m off the lake front (residence time~3 months). But in most of the reported cases the concentration in the bank filtrate is much lower than in the surface water. Since this concentration decline is not only due to dilution, long term bank filtration appears to have the capability to reduce trace organic pollutant concentrations. It would be of great practical value to classify the important trace organic pollutants by degradability during bank filtration and to evaluate the conditions that are favorable for the removal of certain compounds. This study begins to clarify these issues for a few trace organic pollutants. The factors of influence for degradation are studied for model compounds that represent groups of trace pollutants. Additionally, the infiltration process is characterized by several bulk-organic parameters. The goal of the study is to provide a tool that can be merged with hydrogeological models and soil properties to predict the removal efficiency of a given field site.

In Berlin, 70 % of the drinkinq water is derived from bank filtrate or artificially recharged water. Because the surface water system contains elevated proportions of secondary treated municipal sewage, a number of sewage indicators from various sources can be detected in the bank filtrate. An artificial recharge site and a bank filtration site in Berlin Tegel are introduced and compared in terms of their hydrogeological and hydrochemical properties. Because of a permanent clogging layer and the geological properties, travel times are slower at the BF site and the hydrochemical conditions are more reducing. First estimates for the reaction rate constants of oxygen and nitrate are obtained with exponential data fitting. Some of the effects of the different redox conditions on minor substances such as drug residues are highlighted.

Induced by well abstraction, surface water infiltrates into Berlin aquifers and is used for drinking water production. A major advantage of bank filtration is the capability of the subsurface to remove contaminants and save natural groundwater resources. Since a large proportion of the surface water in Berlin originates from treated effluents released by wastewater treatment plants, certain wastewater residues can be traced into the groundwater. A powerful tool to characterise bank filtration systems is the use of wastewater indicators and additional environmental tracers to estimate flow velocities and proportions of bank filtrate in the abstraction wells prior to reactive transport evaluations. Examples for tracer applications at the Berlin system are introduced in this paper. In addition, an overview on results of various studies conducted on contaminant transport and removal during underground passage of the bank filtrate in Berlin is given.

The spatial distribution of confining layers within a system of two aquifers strongly affects the hydraulics and sensitivity to pollution. The test site is located close to a well field. Wells are switched with short intervals and hydraulic heads are recorded in several observation wells. Because the absolute levels of simulated hydraulic heads do not always coincide with the measurements, the model is calibrated with short term head variations. The characteristic shape of the hydraulic heads at each observation wells contains sensitive information about the structure of the aquifer. A numerical technique is developed which enables to simulate the spatial distribution of the confining layer. The method comprises the use of pilot points and regularisation technique. Cross validation is carried out in order to show the results are physically based. The method is shown to provide significant results even under non optimal conditions.

Bank filtration and artificial groundwaterecharge are important, effective and cheap techniques for surface water treatment and removal of microbes, inorganic and some organic contaminants. Nevertheless, mechanisms of the removal of impurities and of the chemical reactions of the water components have not been understood sufficiently and are therefore subject of this research project. The interdisciplinary project of the Berlin Centre of Competence for Water (KWB gGmbH) entitled NASRI (Natural and Artificial Systems for Recharge and Infiltration) concentrates among other topics also on nicroorganisms and trace organic substances frequently detected in surface waters.

The city of Berlin is using bank filtered surface water and artificially recharged water for drinking water production. As far as some hydrological trends and development of anthropogenic pollutants may threat the future of the ground water resource in Berlin, it is important to measure the capacity of ground filtration to answer to such developments, and to secure the use of this systems through the development of the most appropriate practices and the related technologies. This was an obvious reason to initiate a multidisciplinary cooperation project at the Berlin Centre of Competence with the topic "bank filtration and artificial recharge" named Natural and Artificial Systems for Recharge and Infiltration (NASRI). It will focus, for example on questions of the emergence and removal of pharmaceutical residues during bank filtration. The fate and the destination of other specific trace substances as well as of bacteria and viruses are other objectives of the research programme (KWB 2002).